# On mass polarization terms

In Jensen's Introduction to Computational Chemistry it says that the total non-relativistic Hamiltonian operator, transformed to the center of mass system, can be written, in atomic units, as $$\hat{H}=\hat{T}_N+\hat{H}_e+\hat{H}_{mp}$$ where $$\hat{T}_N$$ is the kinetic energy of the nuclei, $$\hat{H}_e$$ is the electronic Hamiltonian, and $$\hat{H}_{mp}$$ is the mass polarization term, written as $$\hat{H}_{mp}=-\frac{1}{2M_{tot}}\left(\sum_{i}^{N_{elec}}\nabla_i\right)^2$$ It happens that I did the transformation step-by-step and found that the mass polarization term should be $$\hat{H}_{mp}=-\frac{1}{2M_{tot}}\sum_{i}^{N_{elec}}\sum_{j\neq i}^{N_{elec}}\nabla_i\cdot\nabla_j$$ So, my first question is, why the textbook consider the case where $$j=i$$ to be the only one? This is also strange, because in my derivation I only found mixed $$j\neq i$$ terms. To be sure about this I tried with a three particle Hamiltonian and got the same. No terms with $$j=i$$.

The other question is, if this term arises because it is not possible to separate the center of mass motion from the internal motion, then, how important is the contribution of mass polarization relative to non-adiabatic coupling elements (beyond Born-Oppenheimer approximation)?