Update: Sorry, I realize now this isn't exactly what you wanted. But I'll leave it here anyway based on feedback in the comments.
I used the structure manipulation scripts provided by AIRSS to generate the conventional cell associated with your primitive cell. I think AIRSS uses Spglib under the hood for this task, so you could probably use Spglib directly if you wanted.
Original cell
New cell
POSCAR file
1.0000000000000000
10.0886200000 0.0000000000 0.0000000000
0.0000000000 7.1337300000 0.0000000000
-2.5221540330 0.0000000000 10.0886187273
A B
16 48
Direct
0.0000000000 0.0000000000 0.0000000000
0.4375000000 0.5000000000 0.7500000000
0.0937500000 0.2500000000 0.8750000000
0.0312500000 0.2500000000 0.6250000000
0.6875000000 0.5000000000 0.7500000000
0.0937500000 0.7500000000 0.8750000000
0.0312500000 0.7500000000 0.6250000000
0.5625000000 0.5000000000 0.2500000000
0.5000000000 0.5000000000 0.0000000000
0.9375000000 0.0000000000 0.7500000000
0.5937500000 0.7500000000 0.8750000000
0.5312500000 0.7500000000 0.6250000000
0.1875000000 0.0000000000 0.7500000000
0.5937500000 0.2500000000 0.8750000000
0.5312500000 0.2500000000 0.6250000000
0.0625000000 0.0000000000 0.2500000000
0.3750000000 0.5000000000 0.5000000000
0.2187500000 0.2500000000 0.3750000000
0.3125000000 0.5000000000 0.2500000000
0.1562500000 0.2500000000 0.1250000000
0.2500000000 0.5000000000 0.0000000000
0.1875000000 0.5000000000 0.7500000000
0.1250000000 0.5000000000 0.5000000000
0.2187500000 0.7500000000 0.3750000000
0.9687500000 0.2500000000 0.3750000000
0.0625000000 0.5000000000 0.2500000000
0.1562500000 0.7500000000 0.1250000000
0.9062500000 0.2500000000 0.1250000000
0.8437500000 0.2500000000 0.8750000000
0.9375000000 0.5000000000 0.7500000000
0.7812500000 0.2500000000 0.6250000000
0.8750000000 0.5000000000 0.5000000000
0.9687500000 0.7500000000 0.3750000000
0.8125000000 0.5000000000 0.2500000000
0.9062500000 0.7500000000 0.1250000000
0.7500000000 0.5000000000 0.0000000000
0.8437500000 0.7500000000 0.8750000000
-0.0000000000 0.5000000000 0.0000000000
0.7812500000 0.7500000000 0.6250000000
0.6250000000 0.5000000000 0.5000000000
0.8750000000 0.0000000000 0.5000000000
0.7187500000 0.7500000000 0.3750000000
0.8125000000 0.0000000000 0.2500000000
0.6562500000 0.7500000000 0.1250000000
0.7500000000 0.0000000000 0.0000000000
0.6875000000 0.0000000000 0.7500000000
0.6250000000 0.0000000000 0.5000000000
0.7187500000 0.2500000000 0.3750000000
0.4687500000 0.7500000000 0.3750000000
0.5625000000 0.0000000000 0.2500000000
0.6562500000 0.2500000000 0.1250000000
0.4062500000 0.7500000000 0.1250000000
0.3437500000 0.7500000000 0.8750000000
0.4375000000 0.0000000000 0.7500000000
0.2812500000 0.7500000000 0.6250000000
0.3750000000 0.0000000000 0.5000000000
0.4687500000 0.2500000000 0.3750000000
0.3125000000 0.0000000000 0.2500000000
0.4062500000 0.2500000000 0.1250000000
0.2500000000 0.0000000000 0.0000000000
0.3437500000 0.2500000000 0.8750000000
0.5000000000 0.0000000000 0.0000000000
0.2812500000 0.2500000000 0.6250000000
0.1250000000 0.0000000000 0.5000000000